borohydride lewis structure


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From: Comprehensive Organic Synthesis, 1991, C. Ponce de Leon, F.C. ), metal oxides (TiO2, V2O5, ZrO2, SnO2, etc. The reduction–hydroboration of alkenes with lithium borohydride/ethyl acetate affords dialkylborinates, whereas alkynes give rise either to vinylboronates or vinylborinates, depending on the structure and reactivity of the alkyne and the stoichiometry.90 The regioselectivity of the addition to terminal alkenes is similar to borane/THF but with phenylacetylene and phenylpropyne the boron atom is preferentially placed in the α-position to the phenyl ring. Combining a 2:1 molar ratio of LiBH4 and MgH2 resulted in a 25 kJ/mol of H2 reduction in the decomposition enthalpy relative to pure LiBH4 due to the formation of MgB2, instead of B, consequently decreasing the decomposition temperature by 250 K [86]. The proposed reaction course is shown in Scheme 5. It has been determined that bimetallic catalysts usually show a higher activity and stability than the monometallic ones. Borohydride reduction of 3-ethoxycarbonyl-4H-pyran 6b afforded primary alcohol 269a (89AP617). In contrast, the carboxylic group is readily reduced with borane/THF. ), and carbon-based materials have been widely studied as catalysts for reducing the decomposition temperature of LiBH4. Recently, various transition metals (Ti, V, Cr, Sc, Pd, Ni, etc. The scandium borohydride thf complex was mentioned in CCC (1987).1 There have been more developments in the borohydride chemistries of scandium and yttrium and so some literature prior to 1982 has been included in this section. Functional groups such as ester, amide, alkyl halide, tosylate, or methanosulfonate are tolerated.95 An interesting result is the hydroboration of unprotected 10-undecenoic acid (Scheme 6). In the Lewis structure of BF4- there are a total of 32 valence electrons. In the solid state the complexes exists as a pseudooctahedral monomer with trans-THF ligands and tridentate borohydride groups.318,483,484 The tetrahydrothiophene analog of U(MeBH3)4 is not isostructural. The scandium compound is trigonal bipyramidal coordinating two thf molecules and is 10-coordinate.83 A doubly bridged borohydride also occurs in the tetrahydridoboratometallocene [Sc{(SiMe3)2Cp}2BH4].84 The yttrium compound [Y(BH4)3(thf)3] coordinates three thf molecules and has a coordination number of 11.61 There is also a second ionic form of the yttrium borohydride [Y(BH4)2(thf)4][Y(BH4)4].60 In the ionic compound [Y(BH4)2(thf)4][Y(BH4)4] the yttrium is 10-coordinate in the cation and 12-coordinate in the anion. Draw the Lewis Structure of borohydride (BH 4-) ion. As in the case of trivalent borohydride complexes, a number of base adducts have been prepared and characterized. We use cookies to help provide and enhance our service and tailor content and ads. The scandium and yttrium borohydrides have also been prepared solvated with dimethoxyethane.85,86 Solution multinuclear NMR studies87 of the scandium and yttrium borohydrides have been carried out, including 45Sc and 89Y measurements. Fisher, in Comprehensive Coordination Chemistry II, 2003. Such borohydride complexes are often prepared by the action of NaBH 4 (or the LiBH 4) on the corresponding metal halide. In the case of adducts of U(BH4)4, the size of the base can control the dimensionality of the resulting product. They synthesized lithium borohydride (LiBH4) from diborane (B2H6):[4][5], Current methods involve reduction of trimethyl borate with sodium hydride.[2]. Electrode and membrane materials are considered together with the importance of operating parameters on the performance of direct borohydride fuel cells. Also, catalysts, such as TiCl3, TiF3, NbF5, CeCl3, have been introduced into the destabilization systems for further reducing the dehydrogenation temperature and improving the hydrogen release/uptake kinetics. Apparently, the LiBH4–0.2MgCl2–0.1TiCl3 composite exhibits the optimal hydrogen storage properties, in which approximately 5 wt% of hydrogen was released at 333–673 K, and 4.5 wt% of hydrogen was rehydrogenated at 873 K and 7 MPa. Th(BH4)4 and Pa(BH4)4 are reported to be isostructural with the major form of U(BH4)4.466,475 In contrast, the neptunium and plutonium compounds are monomeric, with a pseudotetrahedral arrangement of tridentate borohydride groups surrounding the metal center.475, Substituted analogues An(MeBH3)4 (An = Th, Pa, U, Np) have been prepared either by reaction of An(BH4)4 with BMe3 (see Equation (32)),476 or by metathesis routes employing LiBH3Me (see Equation (33)):477–479. The countercation also influences the reducing power of the reagent. Not only this escape of hydrogen generated during the BOR lowers the fuel efficiency of the DBFC, it also raises safety issues. Use of the slightly larger Prn2O ligand results in the formation of an unusual dimer formulated as (Prn2O)2(η3-BH4)3U(μ-η2,η2-BH4)U(η3-BH4)4481 (see Figure 39).

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